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Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes.

ABSTRACT: This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane-porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal-metal fixed-distance Cu/Zn complexes.

SUBMITTER: Knoll DM

PROVIDER: S-EPMC9072197 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes.

Knoll Daniel M DM Wiesner Thomas B TB Marschner Stefan M SM Hassan Zahid Z Weis Patrick P Kappes Manfred M Nieger Martin M Bräse Stefan S

RSC advances 20190926 52

This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane-porphyrin conjugates <i>via</i> palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal-metal fixed-distance Cu/Zn complexes. ...[more]

PMID: 35530211

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