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Low pH constructed Co(ii) and Ni(ii) 1D coordination polymers based on C_α-substituted analogues of zoledronic acid: structural characterization, and spectroscopic and magnetic properties.

ABSTRACT: Three novel coordination compounds based on α,α-disubstituted analogues of zoledronic acid with a cyclopropane (cpp) or cyclobutane (cbt) ring on the C_α carbon, isomorphous [Co(H₂cppZol)(H₂O)]·H₂O (1a), [Ni(H₂cppZol)(H₂O)]·H₂O (1b) and [Co(H₂cbtZol)(H₂O)]·H₂O (2a), were synthesized under hydrothermal conditions at low pH. Single-crystal X-ray diffraction analysis revealed that all the compounds had a 1D double zig-zag chain architecture with an 8 + 8 ring motif formed by alternately arranged symmetrical (-O-P-O-)₂ bridges linking equivalent octahedral metal centres. Both the ligand coordination mode and chain architecture displayed by 1a, 1b and 2a are unique among 1D [M

SUBMITTER: Rojek T

PROVIDER: S-EPMC9072500 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Low pH constructed Co(ii) and Ni(ii) 1D coordination polymers based on C_α-substituted analogues of zoledronic acid: structural characterization, and spectroscopic and magnetic properties.

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Dataset Information

Low pH constructed Co(ii) and Ni(ii) 1D coordination polymers based on Cα-substituted analogues of zoledronic acid: structural characterization, and spectroscopic and magnetic properties.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Low pH constructed Co(ii) and Ni(ii) 1D coordination polymers based on C_α-substituted analogues of zoledronic acid: structural characterization, and spectroscopic and magnetic properties.