Changes in magnetic order through two consecutive dehydration steps of metal-phosphonate diamond chains.

ABSTRACT: Hydrothermal reactions of the multitopic ligand 1-hydroxy-1-(piperidin-4-yl)methylidenebisphosphonic acid (hpdpH₄) with cobalt or nickel sulfates afforded two new isostructural metal phosphonates, M₃ ^II(hpdpH)₂(H₂O)₆·4H₂O [M = Co (Co-10H₂O), Ni (Ni-10H₂O)]. Their structures consist of parallel diamond chains of three MO₆ octahedra bridged by the PO₃C tetrahedra. Six of the seven oxygen atoms of the ligand are involved in coordination; for two ligands that amounts to 12 bonds for 3 MO₆ and the remaining six are occupied by terminal water molecules. In addition, four water molecules sit in between the chains providing H-bonds to the formation of a 3D-net. Therma

SUBMITTER: Su YH 

PROVIDER: S-EPMC9072711 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature