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K0.36(H2O) y WS2: a new layered compound for reversible hydrated potassium ion intercalation in aqueous electrolyte.


ABSTRACT: This work reports the synthesis of a new quasi two-dimensional layered compound, K0.36(H2O) y WS2, for aqueous potassium ion storage. Its crystal structure determined by single crystal X-ray diffraction is composed of WS2 layers and disordered hydrated K+ stacking along the c direction alternately. Due to the large interlayer spacing and high conductivity, K0.36(H2O) y WS2 is demonstrated to be a stable host for reversible intercalation and de-intercalation of hydrated K+ in K2SO4 aqueous solution.

SUBMITTER: Mao Y 

PROVIDER: S-EPMC9073370 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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K<sub>0.36</sub>(H<sub>2</sub>O) <sub><i>y</i></sub> WS<sub>2</sub>: a new layered compound for reversible hydrated potassium ion intercalation in aqueous electrolyte.

Mao Yuanlv Y   Xie Miao M   Zhao Wei W   Yuan Kaidi K   Fang Yuqiang Y   Huang Fuqiang F  

RSC advances 20191010 55


This work reports the synthesis of a new quasi two-dimensional layered compound, K<sub>0.36</sub>(H<sub>2</sub>O) <sub><i>y</i></sub> WS<sub>2</sub>, for aqueous potassium ion storage. Its crystal structure determined by single crystal X-ray diffraction is composed of WS<sub>2</sub> layers and disordered hydrated K<sup>+</sup> stacking along the <i>c</i> direction alternately. Due to the large interlayer spacing and high conductivity, K<sub>0.36</sub>(H<sub>2</sub>O) <sub><i>y</i></sub> WS<sub>2  ...[more]

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