Effect of Band Bending in Photoactive MOF-Based Heterojunctions.

ABSTRACT: Semiconductor/metal-organic framework (MOF) heterojunctions have demonstrated promising performance for the photoconversion of CO₂ into value-added chemicals. To further improve performance, we must understand better the factors which govern charge transfer across the heterojunction interface. However, the effects of interfacial electric fields, which can drive or hinder electron flow, are not commonly investigated in MOF-based heterojunctions. In this study, we highlight the importance of interfacial band bending using two carbon nitride/MOF heterojunctions with either Co-ZIF-L or Ti-MIL-125-NH₂. Direct measurement of the electronic structures using X-ray photoelectron spectroscopy (XPS), work function, valence band, and band gap measurements led to the construction

SUBMITTER: Schukraft GEM 

PROVIDER: S-EPMC9073837 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature