Transference Number in Polymer Electrolytes: Mind the Reference-Frame Gap.

ABSTRACT: The transport coefficients, in particular the transference number, of electrolyte solutions are important design parameters for electrochemical energy storage devices. The recent observation of negative transference numbers in PEO-LiTFSI under certain conditions has generated much discussion about its molecular origins, by both experimental and theoretical means. However, one overlooked factor in these efforts is the importance of the reference frame (RF). This creates a non-negligible gap when comparing experiment and simulation because the fluxes in the experimental measurements of transport coefficients and in the linear response theory used in the molecular dynamics simulation are defined in different RFs. In this work, we show that, by applying a proper RF transformation, a much impro

SUBMITTER: Shao Y 

PROVIDER: S-EPMC9074101 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature