Synthesis of self-assembled nucleobases and their anhydrous proton conductivity.

ABSTRACT: We synthesized self-assembled nucleobases (SANs), such as 1-dodecylthymine (DOT) or 9-dodecyladenine (DOA), in which the nucleobase is immobilized on a long alkyl chain. The thermal stability of the SAN was increased by mixing with the acidic surfactant mono-dodecyl phosphate (MDP). Additionally, the SAN-MDP composite material showed proton conductivity of 4.62 × 10^-4 S cm^-1 at 160 °C under anhydrous conditions. Additionally, the activation energy of the proton conduction was approximately 0.2 eV and this value was one order of magnitude higher than that of a typical humidified perfluorinated membrane, in which the proton can be moved by vehicle molecules, such as water molecules. In contrast, when the nucleobase without the immobilization of a long alkyl chain was mixed with MDP, the proton conductivity of these composite materials was two orders of magnitude less than that of the SAN-MDP composite. Therefore, we measured the XRD spectra of the SAN-MDP composite material. As a result, the SAN-MDP composite material showed a self-assembled structure with a two-dimensional proton conducting pathway, such as a lamellar structure, and that the anhydrous proton conduction was related to the interaction between the nucleobase of the SAN and the phosphate group of MDP. Consequently, the self-assembled nucleobase derivatives have the potential for use as novel anhydrous proton conductors with a two-dimensional proton conducting pathway.

SUBMITTER: Yamada M 

PROVIDER: S-EPMC9074914 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature