Dataset Information

Synthesis and properties of hyperbranched polymers for white polymer light-emitting diodes.

ABSTRACT: In this work, a series of hyperbranched copolymers with fluorene-alt-carbazole as the branches, three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the core, and iridium 1-(4-bromophenyl)-isoquinoline (acetylacetone) (Ir(Brpiq)₂acac) as the dimming group were synthesized by one-pot Suzuki polycondensation for white emission. All copolymers show great thermal stabilities and high hole-transporting ability due to the introduction of the carbazole unit. The hyperbranched structures for copolymers can suppress the interchain interactions efficiently, and help to form amorphous films. The fabricated polymer light-emitting devices (PLEDs) based on the above synthesized copolymers realize good white light emission, and achieve high electroluminescence (EL) performance. For example, for the optimized PLED, the maximum luminance and current efficiency reach 6210 cd m^-2 and 6.30 cd A^-1, respectively, indicating the synthesized hyperbranched copolymers have potential application in solution-processable white polymer light-emitting diodes.

SUBMITTER: Li X

PROVIDER: S-EPMC9074947 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Synthesis and properties of hyperbranched polymers for white polymer light-emitting diodes.

Li Xuefeng X Zhao Haocheng H Gao Long L Xie Xiaoling X Zhang Weixuan W Wang Mixue M Wu Yuling Y Miao Yanqin Y Wang Hua H Xu Bingshe B

RSC advances 20191105 62

In this work, a series of hyperbranched copolymers with fluorene-<i>alt</i>-carbazole as the branches, three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the core, and iridium 1-(4-bromophenyl)-isoquinoline (acetylacetone) (Ir(Brpiq)<sub>2</sub>acac) as the dimming group were synthesized by one-pot Suzuki polycondensation for white emission. All copolymers show great thermal stabilities and high hole-transporting ability due to the introduction of the carbazole unit. The ...[more]

PMID: 35540583

Similar Datasets

Project description:A new series of hyperbranched polymers consisting of fluorene-alt-carbazole as the branches and the three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the core were designed and synthesized by one-pot Suzuki coupling polycondensation. A phosphor group with broad full width at half maximum (FWHM) bis(1-phenyl-isoquinoline)(acetylacetonato)iridium(iii) (Ir(Brpiq)2acac, 0.08 mol%) as the red-light emitting unit and bis(2-(4-bromophenyl)-1-[6-(9-carbazolyl)hexyl]-imidazole)(2-(5-(4-fluorinated phenyl)-1,3,4-triazole)pyridine)iridium(iii) ((CzhBrPI)2Ir(fpptz)) as the green-light emitting unit were introduced into the backbones to obtain sunlight-style white-light emission by adjusting the feeding ratios of (CzhBrPI)2Ir(fpptz) (0.08 to 0.32 mol%). The results indicate the synthesized polymers show high thermal stabilities and good amorphous film morphology because of the hyperbranched structures. Besides, the lowest unoccupied molecular orbital (LUMO) levels of polymers were reduced and the electron injection was improved because of excellent electron-transporting ability of the triazole unit in the green group. The hyperbranched structures can effectively suppress the polymers' chain distortion and aggregation, and promote the incomplete Förster resonance energy transfer (FRET) efficiency from fluorene-alt-carbazole segments to Ir complex units. As a result, the devices with hyperbranched polymer light-emitting layers realize white light emission, and the optimized device also exhibits good electroluminescent (EL) performance with Commission Internationale de l'Eclairage (CIE) coordinates at (0.32, 0.31), a maximum luminance of 9054 cd m-2, a maximum current efficiency of 3.59 cd A-1 and a maximum Color Rendering Index (CRI) of 91. The hyperbranched polymers based on fluorene-alt-carbazole branches and a SDF core and high-efficiency phosphor groups with broad full width at half maximum are attractive candidates for sunlight-style white polymer light-emitting device.

Dataset Information

Synthesis and properties of hyperbranched polymers for white polymer light-emitting diodes.

Publications

Synthesis and properties of hyperbranched polymers for white polymer light-emitting diodes.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets