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N-Enriched carbon nanofibers for high energy density supercapacitors and Li-ion batteries.


ABSTRACT: Nitrogen enriched carbon nanofibers have been obtained by one-step carbonization/activation of PAN-based nanofibers with various concentrations of melamine at 800 °C under a N2 atmosphere. As synthesised carbon nanofibers were directly used as electrodes for symmetric supercapacitors. The obtained PAN-MEL fibers with 5% melamine stabilised at 280 °C and carbonized at 800 °C under a nitrogen atmosphere showed excellent electrochemical performance with a specific capacitance of up to 166 F g-1 at a current density of 1A g-1 using 6 M KOH electrolyte and a capacity retention of 109.7% after 3000 cycles. It shows a 48% increase as compared to pristine carbon nanofibers. Two electrode systems of the CNFM5 sample showed high energy densities of 23.72 to 12.50 W h

SUBMITTER: Kale SB 

PROVIDER: S-EPMC9075030 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature