Selective sensing and visualization of pesticides by ABW-type metal-organic framework based luminescent sensors.

ABSTRACT: A new ABW-type luminescent metal-organic framework (MOF) namely (H₃O)[Zn₂L(H₂O)]·3NMP·6H₂O (1), constructed with eco-friendly Zn²⁺ and the multicarboxylate intraligand (LH₅) was designed, synthesized and fully characterized by X-ray single-crystal diffraction, steady-state absorption and emission spectroscopy, and SEM observations. The MOF-based suspension sensor 1 (NMP) demonstrated high sensitivity to low-concentration pesticides of chlorothalonil (CTL), nitrofen (NF), trifluralin (TFL), and 2,6-dichloro-4-nitroaniline (DCN), which was assigned to the synergistic effect of the photoinduced electron transfer and the fluorescence resonance energy transfer. With the highest luminescent detection efficiency (K _SV</

SUBMITTER: Di L 

PROVIDER: S-EPMC9075901 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature