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Selective detection of trinitrophenol by a Cd(ii)-based coordination compound.

ABSTRACT: A Cd(ii)-based coordination compound, [CdI₂(4-nvp)₂] (1), has been synthesized using CdI₂ and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.

SUBMITTER: Dutta B

PROVIDER: S-EPMC9075976 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Selective detection of trinitrophenol by a Cd(ii)-based coordination compound.

Dutta Basudeb B Purkait Rakesh R Bhunia Suprava S Khan Samim S Sinha Chittaranjan C Mir Mohammad Hedayetullah MH

RSC advances 20191126 66

A Cd(ii)-based coordination compound, [CdI2(4-nvp)2] (1), has been synthesized using CdI2 and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of oth ...[more]

PMID: 35540192

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