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A high-efficiency salamo-based copper(ii) complex double-channel fluorescent probe.


ABSTRACT: In this paper, a salamo-based copper(ii) complex probe L-Cu2+ was synthesized, which combined with copper(ii) ions to form L-Cu2+ for the detection of S2- and had a good fluorescence chemical response. Through spectral analysis, we found that S2- could be identified with high sensitivity and selectivity in the presence of various anions and could be used for the detection of S2- by the naked eye. With the addition of S2-, the solution color changed from colorless to bright yellow. UV absorption, fluorescence and other characterization methods were carried out, and the mechanism of action was determined. In addition, we performed a visual inspection of H2S gas, and the probe L-Cu2+ could detect S2- in the gas molecules, revealing its potential application value in biology and medicine.

SUBMITTER: Wei ZL 

PROVIDER: S-EPMC9076392 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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A high-efficiency salamo-based copper(ii) complex double-channel fluorescent probe.

Wei Zhi-Li ZL   Wang Lan L   Guo Shuang-Zhu SZ   Zhang Yang Y   Dong Wen-Kui WK  

RSC advances 20191213 70


In this paper, a salamo-based copper(ii) complex probe L-Cu<sup>2+</sup> was synthesized, which combined with copper(ii) ions to form L-Cu<sup>2+</sup> for the detection of S<sup>2-</sup> and had a good fluorescence chemical response. Through spectral analysis, we found that S<sup>2-</sup> could be identified with high sensitivity and selectivity in the presence of various anions and could be used for the detection of S<sup>2-</sup> by the naked eye. With the addition of S<sup>2-</sup>, the solu  ...[more]

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