Three new coordination polymers based on bis(4-(4H-1,2,4-triazol-4-yl)phenyl)methane: syntheses, structures, multiresponsive luminescent sensitive detection for antibiotics and pesticides, and antitumor activities.

ABSTRACT: Three novel coordination polymers (CPs), namely, {[Ag₂(L)₂(Mo₄O₁₃)·(CH₃CN)]} _n (1), {[Zn(L)(1,4-bdc)₂·2(1,4-H₂bdc)]} _n (2), {[Cd(L)(1,4-bdc)_0.5]} _n (3) have been synthesized under solvothermal conditions by the reaction of bis(4-(4H-1,2,4-triazol-4-yl)phenyl)methane (L) and varied metal salts. Their structures are determined by single X-ray crystal diffraction, and further characterized by elemental analysis, IR, TGA and PXRD. CP 1 with ammonium molybdate as a secondary ligand displays a 2D network with (2,3,3,3,4)-connected net topology and the point symbol of {4·8²}₆{4·8⁴·10}₂{8}, CP 2 and CP 3 wit

SUBMITTER: Wang CS 

PROVIDER: S-EPMC9076602 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature