Structure and magnetism of two chair-shaped hexanuclear dysprosium(iii) complexes exhibiting slow magnetic relaxation.

ABSTRACT: Two novel hexanuclear Dy^III complexes with polyhydroxy Schiff-base ligands, [Dy₆(L¹)₄(μ₃-OH)₄(MeOH)₄]Cl₂·2MeOH·2MeCN (1) and [Dy₆(HL²)₂(μ₃-OH)₂(μ₃-OCH₃)₂(piv)₁₀(MeOH)₂] (2) (H₃L¹ = N,N'-bis(3-methoxysalicylidene)(propylene-2-ol)-1,3-diamine, H₃L² = 2,3-dihydroxypropylimino)methyl)-6-methoxyphenol, piv = pivalate), have been prepared under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction, elemental analyses, thermal analyses, and IR spectroscopy. Each of the hexanuclear complexes is constructed wit

SUBMITTER: Liu ZY 

PROVIDER: S-EPMC9076819 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature