Changing molecular conjugation with a phenazine acceptor for improvement of small molecule-based organic electronic memory performance.

ABSTRACT: Two conjugated small molecules with different molecular conjugation, 4',4''-(diazene-1,2-diyl)bis(2',3',5',6'-tetrafluoro-N,N-diphenyl-[1,1'-biphenyl]-4-amine) (TPA-azo-TPA) and 4,4'-(perfluorophenazine-2,7-diyl)bis(N,N-diphenylaniline) (TPA-ph-TPA), in which the electron donor triphenylamine moiety is bridged using different electron-accepting azobenzene or phenazine blocks, were designed and synthesized. The TPA-ph-TPA molecule with a larger conjugation acceptor regularly formed a nanocrystalline film and the as-fabricated memory devices exhibited outstanding non-volatile write once read many (WORM) memory effects with an ON/OFF ratio ten times higher than that of TPA-azo-TPA. Using theoretical calculations, it was speculated that the memory performance is a r

SUBMITTER: Liu Q 

PROVIDER: S-EPMC9076932 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature