Piperazinium-mediated crosslinked polyimide-polydimethylsiloxane (PI-PDMS) copolymer membranes: the effect of PDMS content on CO₂ separation.

ABSTRACT: We synthesized copolymers consisting mostly of physically stable rigid polyimide (PI) and a low content of highly permeable rubbery polydimethylsiloxane (PDMS), that were crosslinked by CO₂-philic ionic piperazinium groups attached to the side chains of the copolymers. These crosslinked copolymers (xPI-PDMSs) were fashioned into membranes that showed very high levels of thermochemical stability and excellent CO₂ separation performance (P _CO2 of 799 Barrer and CO₂/N₂ permselectivity of 15.7). The inclusion of the piperazinium groups not only endowed these xPI-PDMS membranes with increased selectivity for CO₂, but also good resistance to CO₂ plasticization. The effect of PDMS content on morphology

SUBMITTER: You H 

PROVIDER: S-EPMC9077095 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature