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Direct C-H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts.

ABSTRACT: A copper-catalyzed direct C-H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which has great potential for photodynamic therapy.

SUBMITTER: Ren W

PROVIDER: S-EPMC9078099 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

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Direct C-H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts.

Ren Wenming W Xiang Huaijiang H Peng Chengyuan C Musha Zulipali Z Chen Jingjing J Li Xin X Huang Ruimin R Hu Youhong Y

RSC advances 20180101 10

A copper-catalyzed direct C-H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which has great potential for photodynamic therapy. ...[more]

PMID: 35542398

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