High rate capability by sulfur-doping into LiFePO₄ matrix.

ABSTRACT: Enhanced electrochemical performance of LiFePO₄ for Li-ion batteries has been anticipated by anion doping at the O-site rather than cation doping at the Fe-site. We report on the electrochemical performance of S-doped LiFePO₄ nanoparticles synthesized by a solvothermal method using thioacetamide as a sulfur source. S-doping into the LiFePO₄ matrix expands the lattice due to the larger ionic radius of S^2- than that of O^2-. The lattice parameters a and b increase by around 0.2% with sulfur content, while that of c remains almost unchanged with only 0.03% increase. The S-doping also contributes to the suppression of antisite defects (Fe occupying Li sites), which facilitates the easy migration of Li in the diffusion c

SUBMITTER: Okada K 

PROVIDER: S-EPMC9078183 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature