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Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

ABSTRACT: A novel textile-based nanosilver catalyst was prepared with a facile synthetic method. The textile-supported nanosilver (TsNS) proved to be an excellent heterogeneous catalyst for the reduction of nitroaromatics with a broad substrate scope. It can be recycled for up to 6 times without significantly compromising its catalytic efficacy. The TsNS catalyst was developed into a column reactor, demonstrating its practical application with the advantages of low cost, ease of operation and large scale synthesis capabilities. Scanning electron microscopy (SEM) showed that there were few changes to the catalyst's surface after the reaction. Besides, inductively coupled plasma (ICP) analysis showed that few silver particles leaked, and the interactions between the nitro groups of the nitroaromatics and the nanosilver particles were characterized by X-ray photoelectron spectroscopy (XPS), which lead to the proposal of a four-step mechanism for the reduction reaction.

SUBMITTER: Feng W

PROVIDER: S-EPMC9078239 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

Feng Wei W Huang Tingting T Gao Liqian L Yang Xianfeng X Deng Wenbin W Zhou Rui R Liu Hongjun H

RSC advances 20180207 12

A novel textile-based nanosilver catalyst was prepared with a facile synthetic method. The textile-supported nanosilver (TsNS) proved to be an excellent heterogeneous catalyst for the reduction of nitroaromatics with a broad substrate scope. It can be recycled for up to 6 times without significantly compromising its catalytic efficacy. The TsNS catalyst was developed into a column reactor, demonstrating its practical application with the advantages of low cost, ease of operation and large scale ...[more]

PMID: 35540419

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Project description:The treatment of toxic nitrophenols in industrial wastewater is urgently needed from environmental, health, and economic points of view. The current study addresses the synthesis of the crosslinked vinyl polymer poly(acrylonitrile-co-2-acrylamido-2-methylpropane sulfonic acid) (poly(AN-co-AMPS)) through free radical copolymerization techniques using acrylonitrile (AN) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) monomers with different ratios and potassium persulfate (KPS) as an initiator in an aqueous medium. The prepared copolymer was utilized as a supporting matrix for silver nanoparticles (AgNPs) via the chemical reduction of silver nitrate within the copolymer framework. Different techniques were employed to characterize the prepared poly(AN-co-AMPS) and Ag/poly(AN-co-AMPS) composites, such as Fourier transform infrared (FTIR) spectroscopy, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), and Brunauer-Emmett-Teller (BET) analysis. The results exhibit that silver metal was excellently dispersed across the surface of poly(AN-co-AMPS) without any agglomeration, presenting as nanocrystals with an average particle size equal to 6.21 nm. Also, BET analysis confirmed that the Ag/poly(AN-co-AMPS) composite exhibits mesoporous characteristics with a surface area of 59.615 m2 g-1. Moreover, the Ag/poly(AN-co-AMPS) composite was effectively applied as a heterogeneous catalyst for the catalytic reduction of hazardous 4-nitrophenols (4-NP) with a rate constant equal to 0.28 min-1 and half-life time equal to 2.47 min to a less toxic compound in the presence of NaBH4 as a reductant. Furthermore, the reusability experiment confirmed the excellent stability of Ag/poly(AN-co-AMPS). The catalyst can be easily separated from the reaction mixture using a simple centrifuge and directly reused for up to four successive cycles without a remarkable decrease in its catalytic activity. The conversion percentage of 4-NP after the four cycles was found to be 93%.

Dataset Information

Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

Publications

Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

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