Dataset Information

Bistable electrical switching and nonvolatile memory effects by doping different amounts of GO in poly(9,9-dioctylfluorene-2,7-diyl).

ABSTRACT: Poly(9,9-dioctylfluorene-2,7-diyl) (PFO) was synthesized under a Suzuki coupling reaction, and its structure was proved by Fourier transform infrared (FT-IR) spectroscopy, and hydrogen and carbon nuclear magnetic resonance (¹H-NMR and ¹³C-NMR). A nonvolatile organic memristor, based on active layers of PFO and PFO:GO composite, was prepared by spin-coating and the influence of GO concentration on the electrical characteristics of the memristor was investigated. The results showed that the device had two kinds of conductance behavior: electric bistable nonvolatile flash memory behavior and conductor behavior. With an increase in GO concentration, the device has an increased ON/OFF current ratio, increasing from 2.1 × 10¹ to 1.9 × 10³, a lower threshold voltage (V _SET), decreasing from -1.1 V to -0.7 V, and better stability. The current remained stable for 3 hours in both the ON state and OFF state, and the ON and OFF state current of the device did not change substantially after 9000 read cycles.

SUBMITTER: Xin Y

PROVIDER: S-EPMC9078296 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Bistable electrical switching and nonvolatile memory effects by doping different amounts of GO in poly(9,9-dioctylfluorene-2,7-diyl).

Xin Ying Y Zhao Xiaofeng X Jiang Xiankai X Yang Qun Q Huang Jiahe J Wang Shuhong S Zheng Rongrong R Wang Cheng C Hou Yanjun Y

RSC advances 20180213 13

Poly(9,9-dioctylfluorene-2,7-diyl) (PFO) was synthesized under a Suzuki coupling reaction, and its structure was proved by Fourier transform infrared (FT-IR) spectroscopy, and hydrogen and carbon nuclear magnetic resonance (<sup>1</sup>H-NMR and <sup>13</sup>C-NMR). A nonvolatile organic memristor, based on active layers of PFO and PFO:GO composite, was prepared by spin-coating and the influence of GO concentration on the electrical characteristics of the memristor was investigated. The results ...[more]

PMID: 35540311

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Project description:Understanding the complex crystallization process of semiconducting polymers is key for the advance of organic electronic technologies as the optoelectronic properties of these materials are intimately connected to their solid-state microstructure. These polymers often have semirigid backbones and flexible side chains, which results in a strong tendency to organize/order in the liquid state. Therefore, crystallization of these materials frequently occurs from liquid states that exhibit-at least partial-molecular order. However, the impact of the preexisting molecular order on the crystallization process of semiconducting polymers- indeed, of any polymer-remained hitherto unknown. This study uses fast scanning calorimetry (FSC) to probe the crystallization kinetics of poly(9,9-di-n-octylfluorenyl-2,7-diyl (PFO) from both an isotropic disordered melt state (ISO state) and a liquid-crystalline ordered state (NEM state). Our results demonstrate that the preexisting molecular order has a profound impact on the crystallization of PFO. More specifically, it favors the formation of effective crystal nucleation centers, speeding up the crystallization kinetics at the early stages of phase transformation. However, samples crystallized from the NEM state require longer times to reach full crystallization (during the secondary crystallization stage) compared to those crystallized from the ISO state, likely suggesting that the preexisting molecular order slows down the advance in the latest stages of the crystallization, that is, those governed by molecular diffusion. The fitting of the data with the Avrami model reveals different crystallization mechanisms, which ultimately result in a distinct semicrystalline morphology and photoluminescence properties. Therefore, this work highlights the importance of understanding the interrelationships between processing, structure, and properties of polymer semiconductors and opens the door for performing fundamental investigations via newly developed FSC methodologies of such materials that otherwise are not possible with conventional techniques.

Dataset Information

Bistable electrical switching and nonvolatile memory effects by doping different amounts of GO in poly(9,9-dioctylfluorene-2,7-diyl).

Publications

Bistable electrical switching and nonvolatile memory effects by doping different amounts of GO in poly(9,9-dioctylfluorene-2,7-diyl).

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