Difference in the deactivation of Au catalysts during ethanol transformation when supported on ZnO and on TiO₂.

ABSTRACT: Au nanoparticles of different sizes were supported by the deposition-precipitation method on two metal oxides: ZnO and TiO₂. The resulting catalysts were tested in the ethanol catalytic transformation reaction. Both metal oxide support materials exerted a different influence on the achieved Au particle size as well as on the behavior of the subsequent catalyst, with regard to their initial conversion values, product distribution and stability. While TiO₂ favors the formation of smaller nanoparticles, ZnO offers larger Au particle sizes when prepared under similar conditions. At the same time, TiO₂ produced catalysts which displayed higher initial conversions in comparison with AuZnO catalysts, even when observing catalysts of each series with similar partic

SUBMITTER: Morales MV 

PROVIDER: S-EPMC9078420 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature