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Sodium borohydride-nickel chloride hexahydrate in EtOH/PEG-400 as an efficient and recyclable catalytic system for the reduction of alkenes.

ABSTRACT: An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH₄-NiCl₂·6H₂O in EtOH/PEG-400 under mild conditions. In this catalytic system, a variety of alkenes (including trisubstituted alkene α-pinene) were well reduced and the Ni catalyst could be recycled.

SUBMITTER: Li K

PROVIDER: S-EPMC9078483 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Sodium borohydride-nickel chloride hexahydrate in EtOH/PEG-400 as an efficient and recyclable catalytic system for the reduction of alkenes.

Li Kaoxue K Liu Chuanchao C Wang Kang K Ren Yang Y Li Fahui F

RSC advances 20180219 14

An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH4-NiCl2·6H2O in EtOH/PEG-400 under mild conditions. In this catalytic system, a variety of alkenes (including trisubstituted alkene α-pinene) were well reduced and the Ni catalyst could be recycled. ...[more]

PMID: 35539108

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