Morphology and pervaporation performance of ionic liquid and waterborne polyurethane composite membranes.

ABSTRACT: Blending an aromatic-selective ionic liquid (IL, namely 1-ethyl-3-methylimidazolium hexafluorophosphate, [emim][PF₆]) with waterborne polyurethane (WPU) enabled us to obtain [emim][PF₆]-modified waterborne polyurethane composite membranes. We characterized the structure and properties of the [emim][PF₆]/WPU composite membranes by ATR-FTIR, DSC, UV, SEM, EDX, swelling tests, and pervaporation testing. Characterization of the change in the morphology of the membranes in response to the IL loading indicated that a preferential interaction between the IL and soft segments of WPU was induced by hydrogen bonding. This interaction inhibited a potential interaction with benzene (Bz), which initially lowered the permeability. However, at high IL loading, the IL inco

SUBMITTER: Xi T 

PROVIDER: S-EPMC9078503 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature