Tailoring of pore structure in mesoporous carbon for favourable flavin mediated interfacial electron transfer in microbial fuel cells.

ABSTRACT: Mesoporous carbon (MC) is supposed to be a good candidate for microbial fuel cell (MFC) anodes as it possesses a large specific area for the redox reaction of the electron shuttles and should deliver high power density. However, the power generation performance of MC anodes is often un-satisfying. It seems that a large portion of the pore surface is not available for anodic redox reaction but the reason is not clear. Here, three MCs with different pore sizes and pore shapes were fabricated and used to explore the effect of the pore structure on the bioelectrocatalysis in Shewanella putrefaciens CN32 MFCs. It is interesting that MC with 40-60 nm spheric pores (MC-III) possesses superior bio-electrocatalytic performance to the CMK-3 (MC-I with 3 nm channel like pores) and the one with

SUBMITTER: Tang W 

PROVIDER: S-EPMC9078639 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature