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Preparation and characterization of polyamide 6 fibre based on a phosphorus-containing flame retardant.

ABSTRACT: Intrinsically flame retardant polyamide 6 (FRPA6) was synthesized by melt polycondensation of caprolactam and 9,10-dihydro-10-[2,3-di(hydroxycarbonyl)propyl]-10-phosphaphenanthrene-10-oxide (DDP). Following this, FRPA6 fibres were prepared by melt spinning. The chemical structure, thermal stability, mechanical and combustion properties of FRPA6 were characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, tensile measurements, vertical burning measurements, limiting oxygen index (LOI) measurements, cone calorimetry and scanning electron microscopy. The thermal stability of FRPA6 decreased to a certain extent, but the amount of residual char was improved. FRPA6 containing 5 wt% DDP could achieve a V-0 rating with an LOI value of 33.7%. The spinnability of FRPA6 fibres was good and the tenacity at break reached 3.0 cN dtex^-1 which met the requirements of textiles. The flame retardancy of FRPA6 fibres was definitely improved and the LOI value of FRPA6-5 fabric could reach 28.4%, thereby showing good prospect in applications.

SUBMITTER: Liu K

PROVIDER: S-EPMC9078688 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Preparation and characterization of polyamide 6 fibre based on a phosphorus-containing flame retardant.

Liu Ke K Li Yuanyuan Y Tao Lei L Xiao Ru R

RSC advances 20180201 17

Intrinsically flame retardant polyamide 6 (FRPA6) was synthesized by melt polycondensation of caprolactam and 9,10-dihydro-10-[2,3-di(hydroxycarbonyl)propyl]-10-phosphaphenanthrene-10-oxide (DDP). Following this, FRPA6 fibres were prepared by melt spinning. The chemical structure, thermal stability, mechanical and combustion properties of FRPA6 were characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimet ...[more]

PMID: 35541864

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Project description:The usage of flame retardants in flammable polymers has been an effective way to protect both lives and material goods from accidental fires. Phosphorus flame retardants have the potential to be follow-on flame retardants after halogenated variants, because of their low toxicity, high efficiency and compatibility. Recently, the emerging allotrope of phosphorus, two-dimensional black phosphorus, as a flame retardant has been developed. To further understand its performance in flame-retardant efficiency among phosphorus flame retardants, in this work, we built model materials to compare the flame-retardant performances of few-layer black phosphorus, red phosphorus nanoparticles, and triphenyl phosphate as flame-retardant additives in cellulose and polyacrylonitrile. Aside from the superior flame retardancy in polyacrylonitrile, few-layer black phosphorus in cellulose showed the superior flame-retardant efficiency in self-extinguishing, ~1.8 and ~4.4 times that of red phosphorus nanoparticles and triphenyl phosphate with similar lateral size and mass load (2.5~4.8 wt%), respectively. The char layer in cellulose coated with the few-layer black phosphorus after combustion was more continuous and smoother than that with red phosphorus nanoparticles, triphenyl phosphate and blank, and the amount of residues of cellulose coated with the few-layer black phosphorus in thermogravimetric analysis were 10 wt%, 14 wt% and 14 wt% more than that with red phosphorus nanoparticles, triphenyl phosphate and blank, respectively. In addition, although exothermic reactions, the combustion enthalpy changes in the few-layer black phosphorus (-127.1 kJ mol-1) are one third of that of red phosphorus nanoparticles (-381.3 kJ mol-1). Based on a joint thermodynamic, spectroscopic, and microscopic analysis, the superior flame retardancy of the few-layer black phosphorus was attributed to superior combustion reaction suppression from the two-dimensional structure and thermal nature of the few-layer black phosphorus.

Dataset Information

Preparation and characterization of polyamide 6 fibre based on a phosphorus-containing flame retardant.

Publications

Preparation and characterization of polyamide 6 fibre based on a phosphorus-containing flame retardant.

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