Rapid transformation of heterocyclic building blocks into nanoporous carbons for high-performance supercapacitors.
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ABSTRACT: The ever-increasing global energy consumption necessitates the development of efficient energy conversion and storage devices. Nitrogen-doped porous carbons as electrode materials for supercapacitors feature superior electrochemical performances compared to pristine activated carbons. Herein, a facile synthetic strategy including solid-state mixing of benzimidazole as an inexpensive single-source precursor of nitrogen and carbon and zinc chloride as a high temperature solvent/activator followed by pyrolysis of the mixture (T = 700-1000 °C under Ar) is introduced. The addition of ZnCl2 prevents early sublimation of benzimidazole and promotes carbonization and pore generation. The sample obtained under the optimal carbonization temperature of 900 °C and ZnCl2/ben
SUBMITTER: Ashourirad B
PROVIDER: S-EPMC9079292 | biostudies-literature | 2018 Mar
REPOSITORIES: biostudies-literature
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