A family of multi-spin rare-earth complexes based on a triazole nitronyl nitroxide radical: synthesis, structure and magnetic properties.

ABSTRACT: The combination of Ln^III ions (Gd^III, Tb^III or Dy^III) and a triazole nitronyl nitroxide radical (4-Me-3-NITtrz) as spin carriers results in two mononuclear and one binuclear compounds, namely, [Ln(hfac)₃(4-Me-3-NITtrz)(H₂O)] (Ln = Gd(1), Tb(2); hfac = hexafluoroacetylacetone; 4-Me-3-NITtrz = 2-[3-(4-methyl-l,2,4-triazolyl)]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) and [Dy(hfac)₂(4-Me-3-NITtrz)₂][Dy(hfac)₄]·CHCl₃. Compounds 1 and 2 are isostructural and crystallize in the P1̄ space group, whereas compound 3 crystallizes in the P2₁/n space group. In 1 and 2, the central Ln^III ions are nine-coordinated (LnNO₈) in a distorted

SUBMITTER: Chen PY 

PROVIDER: S-EPMC9080062 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature