A graphene oxide polymer brush based cross-linked nanocomposite proton exchange membrane for direct methanol fuel cells.

ABSTRACT: Functional polymer brush modified graphene oxide (FPGO) with functional linear polysiloxane brushes was synthesized via surface precipitation polymerization (sol-gel) and chemical modification. Then, FPGO was covalently cross-linked to the sulfonated polysulfone (SPSU) matrix to obtain novel SPSU/FPGO cross-linked nanocomposite membranes. Meanwhile, SPSU/GO composite membranes and a pristine SPSU membrane were fabricated as control groups. Reduced agglomeration of the inorganic filler and better interfacial interaction, which are benefit to increase diffusion resistance of methanol and to generate continuous channels for fast proton transportation at elevated temperature, were observed in SPSU/FPGO cross-linked membranes. Moreover, the enhanced membrane stability (thermal, oxidative

SUBMITTER: Yang T 

PROVIDER: S-EPMC9080066 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature