Cobalt and manganese carboxylates for metal oxide thin film deposition by applying the atmospheric pressure combustion chemical vapour deposition process.

ABSTRACT: Coordination complexes [M(O₂CCH₂OC₂H₄OMe)₂] (M = Co, 4; M = Mn, 5) are accessible by the anion exchange reaction between the corresponding metal acetates [M(OAc)₂(H₂O)₄] (M = Co, 1; M = Mn, 2) and the carboxylic acid HO₂CCH₂OC₂H₄OMe (3). IR spectroscopy confirms the chelating or μ-bridging binding mode of the carboxylato ligands to M(ii). The molecular structure of 5 in the solid state confirms a distorted octahedral arrangement at Mn(ii), setup by the two carboxylato ligands including their α-ether oxygen atoms, resulting in an overall two-dimensional coordination network. The thermal decomposition behavior of 4 and 5 was studied by TG-MS, revealing that deca

SUBMITTER: Kretzschmar BSM 

PROVIDER: S-EPMC9080101 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature