Optically active bimesogens incorporating branched central spacers.

ABSTRACT: In the current fascination with liquid crystalline dimers, bimesogens and oligomers the role of the central spacer in these systems has perhaps been somewhat neglected. In compound 1, a phenyl 4-cyanobenzoate bimesogen, the central spacer incorporates a methyl group at the 2-position and is therefore chiral. The helical twisting power of 1, measured in both 5CB and E7, was found to be 0.36 and 0.35 μm^-1 wt%^-1 respectively. Compound 1 exhibited a monotropic chiral nematic phase, however no twist-bend modulated phase was observed. We prepared a number of analogues of 1 incorporating different mesogenic units and observe that those with a small aspect ratio are non mesogenic, whereas those with larger aspect ratios variously exhibit chiral nematic, TB, SmC and SmB phases

SUBMITTER: Mandle RJ 

PROVIDER: S-EPMC9080582 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature