Thermal conductivity of poly(3,4-ethylenedioxythiophene) films engineered by oxidative chemical vapor deposition (oCVD).

ABSTRACT: Oxidative chemical vapor deposition (oCVD) is a versatile technique that can simultaneously tailor properties (e.g., electrical, thermal conductivity) and morphology of polymer films at the nanoscale. In this work, we report the thermal conductivity of nanoscale oCVD grown poly(3,4-ethylenedioxythiophene) (PEDOT) films for the first time. Measurements as low as 0.16 W m^-1 K^-1 are obtained at room temperature for PEDOT films with thicknesses ranging from 50-100 nm. These values are lower than those for solution processed PEDOT films doped with the solubilizing agent PSS (polystyrene sulfonate). The thermal conductivity of oCVD grown PEDOT films show no clear dependence on electrical conductivity, which ranges from 1 S cm^-1 to 30 S cm^-1. It

SUBMITTER: Smith PM 

PROVIDER: S-EPMC9080664 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature