Inhibitory effects of natural organic matter on methyltriclosan photolysis kinetics.

ABSTRACT: This study evaluated the effects and related mechanisms of natural organic matter (NOM) on the photolysis of methyltriclosan (MTCS), a metabolite of triclosan. Addition of two representative NOM isolates, Pony Lake fulvic acid (PLFA-microbial origin) and Suwannee River fulvic acid (SRFA-terrestrial origin), significantly inhibited the direct photolytic rate of MTCS by ∼70%. The MTCS photolytic rate in the presence of PLFA was greater than for SRFA. NOM not only suppressed photolysis by light-shielding, but also produced ROS to oxidatively degrade MTCS and/or triplet NOM (³NOM*) to sensitize degradation. The dual effects of light-screening and photo-sensitization led to an overall decrease in photolysis of MTCS with a positive concentration-dependence. Upon addition of NOM, EPR d

SUBMITTER: Liu W 

PROVIDER: S-EPMC9080868 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature