A CO₂-tunable plasmonic nanosensor based on the interfacial assembly of gold nanoparticles on diblock copolymers grafted from gold surfaces.

ABSTRACT: A general stepwise strategy for the fabrication of CO₂-tunable plasmonic nanosensors was described for the first time, based on gold surface functionalization by CO₂-responsive poly(N,N-diethylaminoethyl methacrylate) (PDEAEMA) brushes via a surface-initiated atom transfer radical polymerization (SI-ATRP) method, then the extremity of PDEAEMA was functionalized by linking the polyacrylamide (PAAm) brushes via ATRP, where they were assembled with gold nanoparticles (AuNPs) efficiently by altering the deposition time. The swelling-shrinking states of the PDEAEMA brushes can be tuned just by passing CO₂ and N₂ through a solution alternately. The unique plasmonic surface-enhanced Raman scattering (SERS) sensing properties

SUBMITTER: Chen H 

PROVIDER: S-EPMC9081106 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature