A novel microporous Tb-MOF fluorescent sensor for highly selective and sensitive detection of picric acid.

ABSTRACT: A new three-dimensional metal-organic framework (MOF) sensor with molecular formula (C₂H₆NH₂)₂[Tb₂(ptptc)₂(DMF)(H₂O)]·DMF·6H₂O (complex 1) has been constructed from terphenyl-3,3',5,5'-tetracarboxylic acid (H₄ptptc) and terbium nitrate under solvothermal conditions. The structure of complex 1 was characterized by single-crystal X-ray diffraction analysis (XRD), elemental analysis, IR spectroscopy and thermogravimetric (TG) analysis, and the purity was further confirmed by powder X-ray diffraction (PXRD) analysis. XRD analysis reveals that complex 1 crystallizes in a triclinic system P1̄ space group and consists of a three-dimensional anionic network which has one-dimensional channels.

SUBMITTER: Ju P 

PROVIDER: S-EPMC9081240 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature