A series of new polyoxometalate-based metal-organic complexes with different rigid pyridyl-bis(triazole) ligands: assembly, structures and electrochemical properties.

ABSTRACT: Five new polyoxometalate (POM)-based metal-organic complexes (MOCs) with different rigid pyridyl-bis(triazole) ligands, namely, H{Co₂(Hpyttz-I)₂(H₂O)₆[CrMo₆(OH)₆O₁₈]}·8H₂O (1), {Co₂(H₂pyttz-I)₂(H₂O)₄[TeMo₆O₂₄]}[Co(H₂O)₆]·3H₂O (2), {Co₃(Hpyttz-II)₂(H₂O)₆[γ-Mo₈O₂₆]}·10H₂O (3), {Ni₃(Hpyttz-II)₂(H₂O)₆[γ-Mo₈O₂₆]}·10H₂O (4), {Ni₃(Hpyttz-III)₂(H₂O)₈[γ-Mo₈O₂₆]}·10H₂O (5) (H

SUBMITTER: Wang X 

PROVIDER: S-EPMC9081470 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature