Hydrazone-based cobalt complexes toward multielectron redox and spin crossover.

ABSTRACT: Hydrazone-based derivatives modified by substitution at different positions were utilized to prepare a series of bis-homoleptic cobalt complexes. One species, [Co^III(L1)₂]⁺ (1), which incorporated deprotonated ligands, adopted a Co(iii) diamagnetic ground state. However, the substituent of a hydrogen atom with a methyl group precluded the possibility of deprotonation upon metal coordination, which led to two species, [Co^II(L2^Me)₂]²⁺ (2) and [Co^II(L3^NO2)₂]²⁺, (3) which underwent a gradual spin crossover with an adjustable substituent effect and a mixed character of low-spin (doublet) and high-spin (quartet) populations in wide temperature ranges. Depending on the electron

SUBMITTER: Huang W 

PROVIDER: S-EPMC9081832 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature