Tailoring the molecular design of twisted dihydrobenzodioxin phenanthroimidazole derivatives for non-doped blue organic light-emitting devices.

ABSTRACT: Three fused polycyclic aryl fragments, namely, naphthyl, methoxynaphthyl, and pyrenyl have been used to construct blue-emissive phenanthroimidazole-functionalized target molecules, i.e., 1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-2-(naphthalen-1-yl)-1H-phenanthro[9,10-d]imidazole (1), 1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-2-(1-methoxynaphthalen-4-yl)-1H-phenanthro[9,10-d]imidazole (2), and 1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-2-(pyren-10-yl)-1H-phenanthro[9,10-d]imidazole (3). The up-conversion of triplets to singlets via a triplet-triplet annihilation (TTA) process is dominant in these compounds due to 2E _T1 > E _S1. The pyrenyl dihydrobenzodioxin phenanthroimidazole (3)-based

SUBMITTER: Jayabharathi J 

PROVIDER: S-EPMC9084391 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature