Fabrication and catalytic properties of ordered cyclopalladated diimine monolayer : investigation on catalytic mechanism.

ABSTRACT: "Channel-like" self-assembled monolayers having aliphatic and aromatic diimines (denoted as Si@1DIS, Si@2DIS and Si@3DIS) immobilized on substrates and their palladacycle monolayers (Si@1DIS-Pd, Si@2DIS-Pd and Si@3DIS-Pd) were prepared and characterized. Their catalytic performances were investigated using the Suzuki coupling reaction as a model. Si@3DIS-Pd showed the highest catalytic activity in water without ligands, and better recyclability than that of Si@2DIS-Pd and Si@1DIS-Pd. The reason was the carbon in the aliphatic diimine of Si@2DIS-Pd and Si@1DIS-Pd was easily hydrolyzed because of the active hydrogen of α-C, resulting in poor recyclability. Control of the amount of catalyst could be achieved by modulating the diameter of the channel-like structure, which also affected the cat

SUBMITTER: Wang L 

PROVIDER: S-EPMC9085729 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature