Synthesis and characterization of tetraphenylammonium salts.

ABSTRACT: The phenyl (Ph) group is a representative substituent in the field of organic chemistry as benzene (the parent molecule) is of fundamental importance. Simple Ph-substituted compounds of common chemical elements are well known. However, extensive structural characterization of tetraphenylammonium (Ph₄N⁺) salts has not been reported. Herein, the synthesis of Ph₄N⁺ salts and their characterization data including the ¹H and ¹³C nuclear magnetic resonance (NMR) spectra and the single-crystal X-ray structure have been presented. An intermolecular radical coupling reaction between an aryl radical and a triarylammoniumyl radical cation was conducted to synthesize the target moieties. The Ph₄N⁺ salts described h

SUBMITTER: Fujita H 

PROVIDER: S-EPMC9085870 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature