Unknown

Dataset Information

0

Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization.

ABSTRACT: α,β-unsaturated esters are usually synthesized for polymer applications. However, the addition of maleate (cis-configuration) to a fluorinated moiety is challenging due to its potential isomerization during esterification. Various synthetic routes were attempted and led to very low conversion or side-products. The immiscibility of both reagents combined with an easy isomerization or attack on the double bond were potential explanations. In this paper, the synthesis of maleates oligo(hexafluoropropylene oxide) is reported by Steglich esterification and the reaction conditions are discussed depending on the molecular weight of the fluorinated moieties. After UV-curing, hydrophobic polymers were obtained by copolymerization with vinyl ethers by electron acceptor-donor systems.

SUBMITTER: Bonneaud C 

PROVIDER: S-EPMC9086334 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization.

Bonneaud Céline C   Decostanzi Mélanie M   Burgess Julia J   Trusiano Giuseppe G   Burgess Trevor T   Bongiovanni Roberta R   Joly-Duhamel Christine C   Friesen Chadron M CM  

RSC advances 20180921 57

α,β-unsaturated esters are usually synthesized for polymer applications. However, the addition of maleate (<i>cis-</i>configuration) to a fluorinated moiety is challenging due to its potential isomerization during esterification. Various synthetic routes were attempted and led to very low conversion or side-products. The immiscibility of both reagents combined with an easy isomerization or attack on the double bond were potential explanations. In this paper, the synthesis of maleates oligo(hexaf  ...[more]

Similar Datasets

Unknown Asymmetric, organocatalytic, three-step synthesis of alpha-hydroxy-(E)-beta,gamma-unsaturated esters.
| S-EPMC2864524 | biostudies-literature
Unknown Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters.
| S-EPMC5947512 | biostudies-literature
Unknown An efficient synthesis of γ-hydroxy-α,β-unsaturated aldehydic esters of 2-lysophosphatidylcholine.
| S-EPMC3071593 | biostudies-literature
Unknown Copper-catalyzed cascade reactions of α,β-unsaturated esters with keto esters.
| S-EPMC4362015 | biostudies-literature
Unknown anti-Selective synthesis of β-boryl-α-amino acid derivatives by Cu-catalysed borylamination of α,β-unsaturated esters.
| S-EPMC9749109 | biostudies-literature
Unknown Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters.
| S-EPMC3541442 | biostudies-literature
Unknown Asymmetric, organocatalytic, three-step synthesis of gamma-hydroxy-(E)-alpha,beta-unsaturated sulfones and esters.
| S-EPMC2628291 | biostudies-literature
Unknown Grubbs cross-metathesis pathway for a scalable synthesis of γ-keto-α,β-unsaturated esters.
| S-EPMC3985456 | biostudies-literature
Unknown Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile.
| S-EPMC5169164 | biostudies-literature
Unknown Application of the diastereoselective photodeconjugation of α,β-unsaturated esters to the synthesis of gymnastatin H.
| S-EPMC3064449 | biostudies-literature