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Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural.

ABSTRACT: Phosphorus pentoxide (P₂O₅)/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P₂O₅ nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C.

SUBMITTER: Jia S

PROVIDER: S-EPMC9086339 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural.

Jia Songyan S He Xinjun X Ma Jiao J Xu Zhanwei Z Wang Kangjun K Zhang Z Conrad ZC

RSC advances 20180919 57

Phosphorus pentoxide (P2O5)/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P2O5 nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C. ...[more]

PMID: 35547699

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