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Effect of electric field on the electrical properties of a self-assembled perylene bisimide.

ABSTRACT: A functionalised perylene bisimide forms two different self-assembled structures in water depending on the solution pH. Structure 1 (formed at pH 6.2) consists of a fibrous structure, whilst structure 2 (formed at pH 9.4) consists of disordered aggregates. Despite being formed from the same molecule, structure 1 shows higher stability under illumination and electric field than structure 2, demonstrating that the nature of the self-assembled aggregate is critical in devices. Interestingly, both structures show p-type behaviour.

SUBMITTER: Saberi Moghaddam R

PROVIDER: S-EPMC9086733 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Effect of electric field on the electrical properties of a self-assembled perylene bisimide.

Saberi Moghaddam Reza R Draper Emily R ER Wilson Claire C Heidari Hadi H Adams Dave J DJ

RSC advances 20180901 59

A functionalised perylene bisimide forms two different self-assembled structures in water depending on the solution pH. Structure 1 (formed at pH 6.2) consists of a fibrous structure, whilst structure 2 (formed at pH 9.4) consists of disordered aggregates. Despite being formed from the same molecule, structure 1 shows higher stability under illumination and electric field than structure 2, demonstrating that the nature of the self-assembled aggregate is critical in devices. Interestingly, both s ...[more]

PMID: 35548836

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