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Synthesis of a one-dimensional atomic crystal of vanadium selenide (V2Se9).


ABSTRACT: The synthesis and nanoscale dispersion of a new one-dimensional (1D) material, V2Se9, in which chain-shaped molecular units with strong covalent bonds are assembled in a crystal structure via weak van der Waals attraction between chains, were successfully carried out. V2Se9 is synthesized by solid-state reaction and additional heat treatment. The synthesized V2Se9 has excellent thermal stability up to 400 °C and has been experimentally confirmed to be dispersed up to ∼20 nm or less through a specific solvent dispersion. The covalently bonded V2Se9 chain, when isolated from its bulk material, is expected to exhibit unique quantum physical properties owing to the confinement of electrons in the 1D

SUBMITTER: Oh S 

PROVIDER: S-EPMC9086741 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature