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Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(vi) complex with H₂O₂ as an oxidant.

ABSTRACT: Here, we have described the synthesis, characterization and catalytic activity of a dioxo-molybdenum(vi) complex supported on functionalized Merrifield resin (MR-SB-Mo). The functionalization of Merrifield resin (MR) was achieved in two-steps viz. carbonylation (MR-C) and Schiff base formation (MR-SB). The compounds, MR-C, MR-SB and MR-SB-Mo, were characterized at each step of the synthesis by elemental, SEM, EDX, thermal, BET and different spectroscopic analysis. The catalyst, MR-SB-Mo, efficiently and selectively oxidized a wide variety of alcohols to aldehydes or ketones using 30% H₂O₂ as an oxidant with reasonably good TOF (660 h^-1 in case of benzyl alcohol). The catalyst acted heterogeneously under solventless reaction conditions and did not lea

SUBMITTER: Boruah JJ

PROVIDER: S-EPMC9086892 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(vi) complex with H₂O₂ as an oxidant.

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Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(vi) complex with H2O2 as an oxidant.

OmicsDI is part of the ELIXIR infrastructure

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Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(vi) complex with H₂O₂ as an oxidant.