Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework.

ABSTRACT: A series of polymeric Mn(ii)-thioarsenates [Mn(en)₃] _n [(N₂H₄)₂Mn₆(μ₆-S)(μ-N₂H₄)₂(μ₃-AsS₃)₄] _n (1), [N₂H₅] _n [{Mn(μ-N₂H₄)₂(μ-AsS₄)}·0.5en] _n (2), [Mn(μ-trien){Mn(μ-N₂H₄)(μ-AsS₃)}₂] _n (3), [{Mn(N₂H₄)}₂(μ-N₂H₄)₂{Mn(μ-N₂H₄)₂(μ-AsS₃)₂}] _n (4), [Mn₃(μ-N₂H₄)₆(μ₃-AsS₄)(

SUBMITTER: Han J 

PROVIDER: S-EPMC9087208 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature