Highly dispersed ruthenium nanoparticles on nitrogen doped carbon toward efficient hydrogen evolution in both alkaline and acidic electrolytes.

ABSTRACT: Efficient and inexpensive electrocatalysts toward the hydrogen evolution reaction (HER) play an important role in electrochemical water splitting. Herein, we report the synthesis of highly dispersed ruthenium nanoparticles (2.2 ± 0.4 nm) on nitrogen doped carbon (Ru/N-C) by chemical reduction of RuCl₃ on carbon in the presence of polyvinylpyrrolidone in combination with subsequent pyrolysis. Ru/N-C exhibits an excellent overpotential of 13.5 and 18.5 mV at 10 mA cm^-2 in 1.0 M KOH and 0.5 M H₂SO₄ aqueous solution, respectively, much better than and comparable to those of commercial Pt/C (38.0 and 10.0 mV). The exceptional HER activity arises from high surface area of ultrafine Ru nanoparticles and appropriate Ru electronic state tuned by nitrogen

SUBMITTER: Li G 

PROVIDER: S-EPMC9088967 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature