Tailoring Oligomeric Plasticizers for Polylactide through Structural Control.

ABSTRACT: Structural variations (oligolactide segments, functionalized end groups, and different plasticizer cores) were utilized to tailor the performances of biobased plasticizers for polylactide (PLA). Six plasticizers were developed starting from 1,4-butanediol and isosorbide as cores: two monomeric (1,4-butanediol levulinate and isosorbide levulinate) and four oligomeric plasticizers with hydroxyl or levulinate ester end groups (1,4-butanediol-based oligolactide, isosorbide-based oligolactide, 1,4-butanediol-based oligomeric levulinate, and isosorbide-based oligomeric levulinate). Structural variations in plasticizer design were reflected in the thermal stability, plasticizing efficiency, and migration resistance. The monomeric plasticizer 1,4-butanediol levulinate decreased the glass-transitio

SUBMITTER: Xuan W 

PROVIDER: S-EPMC9089748 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature