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Experimental and theoretical interpretation of the magnetic behavior of two Dy(iii) single-ion magnets constructed through β-diketonate ligands with different substituent groups (-Cl/-OCH₃).

ABSTRACT: Two Dy(iii) single-ion magnets, formulated as [Dy(Phen)(Cl-tcpb)₃] (Cl-1) and [Dy(Phen)(CH₃O-tmpd)₃] (CH₃O-2) were obtained through β-diketonate ligands (Cl-tcpb = 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione and CH₃O-tmpd = 4,4,4-trifluoro-1-(4-methoxyphenyl)-1,3-butanedione) with different substituent groups (-Cl/-OCH₃) and auxiliary ligand, 1,10-phenanthroline (Phen). The Dy(iii) ions in Cl-1 and CH₃O-2 are eight-coordinate, with an approximately square antiprismatic (SAP, D _4d) and trigonal dodecahedron (D _2d) N₂O₆ coordination environment, respectively, in the first coordination sphere. Under zero direct-current (dc) field, magnetic investigation

SUBMITTER: Zhang S

PROVIDER: S-EPMC9092431 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Experimental and theoretical interpretation of the magnetic behavior of two Dy(iii) single-ion magnets constructed through β-diketonate ligands with different substituent groups (-Cl/-OCH₃).

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Experimental and theoretical interpretation of the magnetic behavior of two Dy(iii) single-ion magnets constructed through β-diketonate ligands with different substituent groups (-Cl/-OCH3).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Experimental and theoretical interpretation of the magnetic behavior of two Dy(iii) single-ion magnets constructed through β-diketonate ligands with different substituent groups (-Cl/-OCH₃).