Catalytic oxygen evolution from hydrogen peroxide by trans-[Co(en)₂Cl₂]@InBTB metal-organic framework catalytic system.

ABSTRACT: The diethylammonium counter-cations of the [Et₂NH₂]₃[In₃(BTB)₄] metal-organic framework (InBTB MOF, BTB = 1,3,5-benzenetribenzoate) with an anionic framework can be effectively exchanged with cationic trans-[Co(en)₂Cl₂]⁺ complex ions through a simple cation-exchange process. The heterogenized trans-[Co(en)₂Cl₂]⁺-encapsulated InBTB MOF (trans-[Co(en)₂Cl₂]@InBTB) catalytic system maintained the activity of the captured trans-[Co(en)₂Cl₂]⁺ complex ion for hydrogen peroxide decomposition in aqueous solution under mild reaction conditions. The captured trans-[Co(en)₂Cl_2</

SUBMITTER: Yoon S 

PROVIDER: S-EPMC9096809 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature