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Emulsion-Templated Porous Polymers for Efficient Dye Removal.


ABSTRACT: A high internal phase emulsion (HIPE) method was used to produce adsorbents with an interconnected porous structure. HIPE was prepared using vinyl benzyl chloride (VBC), divinylbenzene (DVB), tert-butyl acrylate, and Span80 as the organic phase and water with K2S2O8 and CaCl2 as the water phase. The polymerization of the organic phase produced highly porous polymers called polyHIPE, carrying two functional groups. As a result of the template method, polyHIPEs have a low surface area. To overcome this drawback, polyHIPE was hyper-cross-linked through VBC to create meso- and micropores, resulting in a higher surface area. Then the polymer surface was tailored with carboxylic acid groups by simple hydrolysis of tert-butyl acrylate. The

SUBMITTER: Uzum G 

PROVIDER: S-EPMC9097204 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature